本實驗以 PEDOTPSS(PH1000)作為電洞傳輸層，實驗的元件結構為
ITO/PEDOT:PSS_PH1000/Perovskite/PCBM/Al是標準P-I-N結構之一步法製作的鈣鈦礦太陽電池。為了探討Ph1000對元件的表現。透過改變退火時間與退火溫度，比較不同鈣鈦礦的表面。如果我們能有效控制退火溫度和時間，我們可以得到一個很好的鈣鈦礦太陽電池。更重要的是隨著溶液重量百分比的不同，我們需要不同的退火時間和退火溫度去控制鈣鈦礦太陽電池的成膜。讓元件表現更理想。藉由選擇不同材料當作電洞傳輸層來製作出鈣鈦礦太陽電池，我們知道在相同製程參數下，PH1000所製作的元件的電流大小比AI4083的元件大。本論文所提出的方法擁有在低溫條件下製作的好處和優異的穩定性，對未來朝向大面積化太陽電池的發展是相當有優勢的。

We used PEDOTPSS(PH1000) as the hole transport layer. Our device configuration:Glass/ITO/PEDOT:PSS_PH1000/Perovskite/PCNM/Al/.In order to understanding the device performance which is used the PEDOT:PSS_PH1000 as the hole transport layer. We changed the annealing time and annealing temperature to compare the different perovskite surface. If we could control the annealing time and annealing temperature , We would have a good perovskite solar cell. By using the different materials as the hole transport layer,we know that PH1000 device has larger current than AI4083 device at the same process parameters. With its low processing temperature and high stability,our device may be a promising approach for the large-area production of perovskite solar cells.

目錄
第一章 序論 10
1.1 研究背景 10
1.1.1 前言 10
1.1.2 太陽能電池的發展 11
1.1.3 有機太陽電池的發展 12
1.1.4 鉛鹵鈣鈦礦太陽電池的發展 14
1.2 研究動機及文獻回顧 15
1.3 論文架構 20
第二章 實驗原理 22
2.1 Solar cell 基本介紹 22
2.1.1 Solar cell操作理論 22
2.1.2 理想的Solar Cell 23
2.1.3 Solar cell實際等效模型: 25
2.1.4 Solar cell基本參數: 27
2.1.5 Solar cell操作分析: 31
2.2 太陽能電池材料特性與理論 34
2.2.1 選用的主動層吸光材料 34
2.2.2 選用的電子與電洞傳輸層材料 36
2.2.3 選用的正極與負極材料 38
2.3 鈣鈦礦太陽能電池結構 39
第三章 實驗方法與流程 40
3.1 鈣鈦礦太陽電池製作流程 40
3.2 ITO玻璃設計基板與定義圖形 40
3.2.1 ITO基板 41
3.2.2 貼上乾式光阻 41
3.2.3 曝光 41
3.2.4 顯影 42
3.2.5 蝕刻 42
3.3 清洗ITO玻璃 43
3.4 成膜電洞傳輸層 43
3.5 主動層成膜 44
3.6 電子傳輸層成膜 46
3.7 蒸鍍金屬負電極 46
3.8 封裝 47
3.9 量測 48
第四章 實驗數據討論 51
4.1 量測的差異會造成數據的誤差 51
4.2 主動層退火時間與溫度對太陽電池的影響 55
4.3 比較有無LiF對太陽電池的影響 68
4.4 元件壽命 69
4.5 優化鈣鈦礦太陽電池的方法 72
第五章 總結與未來展望 76

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