本研究提出一種新型聚二甲基矽氧烷複合電極材料應用於可撓曲微型質子交換膜燃料電池，以聚二甲基矽氧烷做為基材，藉由微機電技術製作具有微流道結構之電極，透過有機矽烷方法在聚二甲基矽氧烷上修飾上特定官能基，並成長導電層金或導電高分子聚苯胺，分析其導電材料與PDMS基材間的附著力、表面形貌以及可撓曲電性測試，最後在沉積白金觸媒，進行燃料電池相關測試與分析。
　　有機矽烷修飾方法製作之PDMS金電極在附著力與可撓曲電性測試上皆具有非常突出的表現，附著力為ISO等級0，撓曲曲率達2/cm時電阻抗僅上升約8倍。燃料電池部分，半電池測試中，在撓曲曲率達3.333/cm時效能僅下降約6.6%；在全電池測試中，測得最大功率密度在0.321V時為2.55mW/cm2。

In this paper, a novel design of PDMS-based bendable electrodes with microstructures is proposed for flexible proton exchange membrane fuel cells (PEMFCs). The design of the bendable electrodes incorporates micro-structured PDMS-film to increase the reaction area and fuel pass-way, conducting layer Au with strong conjugation to the PDMS-microstructures for electron conduction, and Pt catalyst for fuel reaction.
The electrodes perform ISO class 0 in adhesion test and only increase 6.6% resistance under 2/cm bending curvature. The half-cell test yields a performance of 12.7~13.8mA/cm-2 at 0.6V under serious bending conditions and also 2.55mW/cm2 at 0.321V in fuel cell test.

摘要……………………………………………………………….………i
Abstract……………………………………………….………………….ii
誌謝………………………………………………………..…………….iii
目錄………………………………………………………...……………iv
圖目錄…………………………………………………………………..vii
表目錄……………………………………………………………..........xii
一、 緒論………………………………………………………..........1
1.1前言…………………………………………………………...….1
1.2燃料電池之簡介…………………………………………………1
1.2.1鹼性燃料電池………………………………………………2
1.2.2磷酸燃料電池………………………………………………3
1.2.3融熔碳酸鹽燃料電池………………………………………3
1.2.4固態氧化物燃料電池………………………………………4
1.2.5質子交換膜燃料電池………………………………………4
1.3可撓曲之微型質子交換膜燃料電池研究動機………………….5
二、 文獻回顧………………………………………………………..6
2.1可撓曲燃料電池…………………………………………………6
2.2有機矽烷修飾方法……………………………………………….9
2.3聚苯胺…………………………………………………………...11
2.3.1聚苯胺之簡介……………………………………………..11
2.3.2聚苯胺之摻雜……………………………………………..12
2.3.3聚苯胺之化學合成……………………………………….15
2.3.4聚苯胺作為白金觸媒載體………………………………..16
2.4電池組裝技術…………………………………………………..17
2.5研究方法………………………………………………………..20
三、 聚二甲基矽氧烷複合奈微結構電極之合成與可撓曲微型質子交換膜燃料電池之應用…………………………………………...21
3.1燃料電池基本設計與實驗架構………………………………..21
3.2有機矽烷方法製作PDMS-based平面電極(A)………………..22
3.2.1 PDMS-based電極製作製作原理…………………………..22
3.2.2 PDMS-based電極測試原理………………………………..22
3.2.2.1吸附性測試原理………………………………………..23
3.2.2.2可撓曲電性測試原理…………………………………..24
3.2.3 PDMS-based電極製作實驗藥品與儀器………………….25
3.2.3.1 PDMS-based電極製作實驗藥品……………………...25
3.2.3.2 PDMS-based電極製作實驗儀器………………………26
3.2.4 PDMS-based電極製做步驟流程………………………….29
3.3聚二甲基矽氧烷微結構電極燃料電池製作與測試(B)…….…32
3.3.1聚二甲基矽氧烷微結構電極製作原理……………………32
3.3.2聚二甲基矽氧烷微結構電極燃料電池測試原理…………33
3.3.2.1聚二甲基矽氧烷微結構電極燃料電池測試原理……..33
3.3.2.2聚二甲基矽氧烷微結構電極燃料電池全電池測試原理…………………………………………………….….34
3.3.3實聚二甲基矽氧烷微結構電極實驗藥品與儀器…………36
3.3.3.1聚二甲基矽氧烷微結構電極實驗藥品………………..36
3.3.3.2聚二甲基矽氧烷微結構電極實驗儀器………………..36
3.3.4聚二甲基矽氧烷微結構電極製作步驟流程………………38
四、 結果與討論……………………………………………………41
4.1 PDMS-based平面電極結果與討論……………………………41
4.1.1不同導電材料於PDMS上製作導電薄膜之結果與比較…41
4.1.2不同黏著材料對於Au在PDMS上製作導電薄膜之結果與比較…………………………………………..……………..42
4.1.2.1吸附測試結果………………………………………….42
4.1.2.2可撓曲電性測試結果………………………………….43
4.1.3 Au/MPTMS/PDMS表面形貌………………………….…..51
4.2聚二甲基矽氧烷微結構電極燃料電池測試結果與討論……..52
4.2.1表面形貌分析結果…………………………………………52
4.2.2可撓曲半電池電化學分析結果……………………………53
4.2.3全電池封裝與測試…………………………………………55
4.2.3.1全電池組裝……………………………………………..55
4.2.3.2全電池可撓曲測試架構……………………………….57
4.2.3.3傳統全電池測試架構…………………………………..59
4.3結論……………………………………………………………..62
五、 未來展望……………………………………………………....63
六、 參考文獻………………………………………………………64

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