近年來能源問題以及環境議題備受討論，太陽能作為一種具發展性的可再生能源已經逐漸受到關注，而這當中有機太陽能電池製程有著低成本、輕巧且可重複利用的特性而受到大量的研究以及開發，未來將朝著元件之高光電轉換效率的方向邁進。
　　在有機太陽能電池模組化製程中會進行子元件的串聯，子元件串聯會產生難以發電的部分區域，這個部分區域稱為死區(Dead zone)，有著影響太陽能電池效率決定性的因素。本論文之目的為探討如何優化降低死區製程之模組，其中包含新蒸鍍樣式遮罩、改良製程模組上的各式因素並且做比較來提升元件之能量轉換效率與填充因子，希望可以在固定的量測面積下增加其有效發電區域。



關鍵字:有機太陽能電池、刮刀塗佈製程、填充因子、提升有效發電區域、二元系統

In recent years, energy issues and environmental issues have been much discussed. Solar energy, as a promising renewable energy source, has gradually attracted attention. Among them, the organic solar cell process has received a lot of research due to its low cost, lightweight and reusable characteristics. As well as development, the future will move towards high photoelectric conversion efficiency of components.
In the modularization process of organic solar cells, sub-components are connected in series. The series connection of sub-components will create a partial area where it is difficult to generate electricity. This partial area is called a dead zone, which is a decisive factor affecting the efficiency of solar cells. The purpose of this thesis is to explore how to optimize the module that reduces the dead zone process, including new evaporation style masks, various factors on the improved process module, and make comparisons to improve the energy conversion efficiency and fill factor of the device. I hope it can Increase its effective power generation area under a fixed measurement area.

Keywords:Organic Solar Cell, Blade coating, Fill factor, increase effective power generation area, binary system.

摘要----------------------------------------------i
Abstract-----------------------------------------ii
誌謝---------------------------------------------iii
圖目錄-------------------------------------------vii
表目錄-------------------------------------------xi
第一章 序論---------------------------------------1
1.1研究背景---------------------------------------1
1.1.1前言-----------------------------------------1
1.1.2太陽能電池發展之簡要--------------------------2
1.1.3有機型太陽能電池之發展與介紹-------------------3
1.2研究動機---------------------------------------6
1.2.1有機型太陽能電池之優勢------------------------6
1.2.2有機型太陽能電池之活性層-----------------------8
1.2.3有機型太陽能電池之介面層-----------------------8
1.3文獻回顧----------------------------------------9
1.3.1有機型太陽能電池之活性層材料的選擇--------------9
1.3.2刮刀塗佈技術製作大面積有機型太陽能電池----------10
1.3.3有機型太陽能電池之減少非發電區域---------------11
1.3.4有機型太陽能電池之正式結構、反式結構------------12
1.4論文結構---------------------------------------14
第二章 實驗原理------------------------------------15
2.1太陽能電池之介紹--------------------------------15
2.1.1太陽能電池之工作原理---------------------------15
2.1.2太陽能電池之等效電路及其分析--------------------16
2.1.3太陽能電池之重要參數簡介------------------------19
2.1.4太陽能電池之偏壓點分析--------------------------22
2.2有機型太陽能電池之介紹----------------------------25
2.2.1有機型太陽能電池之材料特性與介紹-----------------25
2.2.2有機半導體之能帶理論----------------------------26
2.3本論文使用之材料與結構介紹-------------------------27
2.3.1正式結構之陽極與反式結構之陰極-------------------27
2.3.2正式結構電洞傳輸層與反式結構電子傳輸層------------28
2.3.3活性層及活性層添加物-----------------------------29
2.3.4正式結構介面層與反式結構電洞傳輸層----------------31
2.3.5正式結構陰極電極與反式結構陽極電極----------------32
2.4正式結構與反式結構及其能帶圖------------------------32
第三章 實驗方法與流程---------------------------------34
3.1有機型太陽能電池製作之流程--------------------------34
3.1.1 ITO基板蝕刻------------------------------------35
3.2 ITO基板清洗--------------------------------------37
3.3材料溶液調配--------------------------------------38
3.4刮刀塗佈技術--------------------------------------38
3.4.1正結構電洞傳輸層與反結構電子傳輸層塗佈-------------39
3.4.2活性層塗佈--------------------------------------41
3.4.3正式結構陰極介面層塗佈---------------------------42
3.5元件之蒸鍍製程------------------------------------43
3.6元件封裝------------------------------------------45
3.7元件量測------------------------------------------46
第四章 實驗結果與討論---------------------------------47
4.1正式結構縮小死區製程-------------------------------47
4.1.1縮小死區之原理----------------------------------47
4.1.2正式結構縮小死區製程測試-------------------------49
4.1.3 PM6：Y6之二元正式結構縮小死區製程---------------56
4.2反式結構縮小死區製程------------------------------58
4.2.1反式結構縮小死區製程測試-------------------------58
4.2.2縮小死區製程活性層溶劑比較-----------------------62
4.2.3縮小死區製程不同氧化鋅配方比較-------------------63
4.2.4縮小死區製程有無緩衝層(PEI)之比較----------------65
4.2.5縮小死區製程三氧化鉬厚度對於效率之比較------------66
4.3縮小死區製程蒸鍍遮罩樣式新設計---------------------67
第五章 結論與未來展望--------------------------------69
參考文獻--------------------------------------------70

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