本論文是以刮刀塗佈方式之溶液製程製造橘光有機發光二極體。主要畫分三大部分，第一部分使用產學合作計畫夥伴昱鐳光電科技股份有限公司提供的HT-N01參雜以TFB為主的電洞傳輸層，在實驗中調整各項製程條件，尋求出較適合的製程方法。
第二部分也是使用昱鐳光電科技股份有限公司提供的HT-N02參雜以TFB為主的電洞傳輸層，並針對配藥比例、下藥量、基板溫度做調整，而實驗結果顯示比例為TFB：HT-N02=9：1、dose量75μl、溫度60°C為較適合的製程條件。
第三部分則是在這學年與陽明合作計畫中，研究在臨床實驗中照度與壽命的實際狀況，為了達到距30cm處30lux的要求，本論文透過不同片數與形狀之燈具測量其輝度、照度以及電壓，可以有效地判斷燈具之效能，而測試結果為7片六邊形燈具的效果最好，隨後模擬臨床實驗，為了達到距30cm處30lux且開燈36小時，本論文以3次12小時的開燈時間做燈具壽命量測，實驗後得出燈具在前12小時的電壓增幅較為劇烈，而在往後12~36小時電壓上升較為平緩，36小時期間電壓從4.71v上升至5.7V，為較理想的狀態。

In this paper,the orange organic light-emiiting diode is made by blade coating.The main experiment is divides into three parts.The first part is the research about HT-N01,provided by cooperation partner,E-Ray Optoelectronics Technology Co.,Ltd,be mixed with TFB-based hole transport layer.In this work,various process are adjusted to find the better condion.
The second part is the research about HT-N02,also provided by E-Ray Optoelectronics Technology Co.,Ltd,being doped with TFB-based hole transport layer.Direct to the propotion of material, dosage and temperature of substrate.The result show that the ratio of TFB：HT-N02 is 9：1,the dosage is 75μl,and the temperature of substrate is 60°C are better than others.
Finally,the third part is the study of thel situation of illuminance and life time in clinical test which is the cooperation project with Professor ,Liou, Yiing-Mei.In order to achieve the requirement of 30 lux at a distance of 30cm,we measure Voltage,Luminance and Illuminance though the lamps with different OLED numbers and shapes.the performance of lamps can be effectively judged.The result show that the 7-segment hexagonal lamp has the best effect.Amd then, in order to achieve the requirement of 30 lux at a distance of 30cm and turn on the lamp for 36 hours, the clinical experiment is simulated.We take 3 times test measuring lamp life for 12 ho hours.After finishing the work, it is found that the voltage of the lamp in the first 12 hours has increased sharply and the voltage rises more slowly in the next 12 to 36 hours. The voltage rises from 4.71 V to 5.7 V in this 36 hours.It is a more ideal state

摘要 I
ABSTRACT II
致謝 IV
目錄 V
圖目錄 VIII
表目錄 X
第一章、 緒論 1
1.1 前言 1
1.2 有機發光二極體發展簡介 1
1.3 論文架構 2
第二章、 有機發光二極體之結構與基礎理論 3
2.1 有機發光二極體結構 3
2.2 研究目的 4
2.3 有機發光二極體發光機制 4
2.4 磷光與螢光 6
2.5 主發光體與客發光體之能量轉移 7
2.4.1 輻射能量轉移 7
2.4.2 非輻射能量轉移 8
第三章、 有機發光二極體之製程與材料介紹 10
3.1 元件製作流程 10
3.1.1 ITO基板蝕刻 10
3.1.2 有機薄膜刮塗 13
3.1.3 蒸鍍與封裝 17
3.1.4 元件電性分析 20
3.2 實驗材料介紹 21
3.2.1 電洞注入材料 21
3.2.2 電洞傳輸層材料 22
3.2.3 電子阻擋層材料 24
3.2.4 電子傳輸層材料 24
3.2.5 客發光體材料 25
第四章、 實驗設計 26
4.1 以HT-N01混TFB為電動傳輸層溶劑元件 26
4.1.1 調整HTN01混合TFB比例 27
4.1.2 調整HTN01混TFB下藥量 30
4.1.3 調整HT-N01混和TFB刮塗時基板溫度 33
4.1.4 HTN01混TFB加磁石加熱攪拌測試 36
4.1.5 HT-N01混合TFB在手套箱內退火測試 39
4.2 以HT-N02混和TFB為電洞傳輸層溶劑元件之效能改善 41
4.2.1 調整HT-N02混和TFB之比例 42
4.2.2 調整HT-N02混和TFB下藥量 45
4.2.3 調整HT-N02混和TFB刮塗時基板溫度 50
4.3 陽明大學合作計畫之元件壽命與輝度測試 54
4.3.1 九片OLED元件之燈具 55
4.3.2 八片OLED元件之燈具 56
4.3.3 七片OLED元件之燈具 59
4.3.4 模擬臨床實驗之元件壽命量測 62
第五章、 結論與未來展望 67
5.1 結論 67
5.2 未來展望 68
第六章、 參考文獻 69

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