本研究致力於合成鑭系金屬錯化合物並進行各項性質和結構分析，希望在金屬原子串 (EMACs)的合成和溶劑熱合成 (Solvothermal synthesis)進行方法學上之整合與探討。在過去的研究當中，多數的金屬串都是由氮原子作為金屬串的電子對提供者，而中心金屬多數為過渡金屬之元素，因此本研究之核心致力於跳脫傳統合成的方法，希望能合成出以氧原子為配基之鑭系金屬錯化合物。此外，鑭系元素在一般的化學領域當中也較少被探討，顯得鑭系元素的研究非常神秘，因此了解其基本性質也是本研究的基礎，如原子半徑、離子半徑、配位數以及電子組態等。
在實驗部分，主要的合成方法為溶劑法，利用不同沸點的溶劑調節反應溫度，並從中觀察不同溶解度對反應的影響，然而此部分的分析結果並未得到準確的單晶結構，因此透過質譜 (LR¬¬ MALDI) 作為主要分析的方法，試圖從同位素分布和分子量的對應找尋目標分子的蹤跡。雖然沒能得到準確的單晶結構，但我們也利用溶劑法和溶劑熱法的整合，成功得到 [La(OAc)2(DMF)(Chrysazin)]n 之單晶結構，並且從此晶格結構中了解其基本的配位數及配位方式。未來也希望以此為基礎，更深入了解鑭系元素的領域，並合成不同的金屬原子串。

This study is devoted to the synthesis of lanthanide metal compounds. The properties and structure analysis are also in processing. We are trying to make a combination of methodologies in the synthesis of metal string and solvothermal synthesis.
Previously, most of the metal strings were provided by nitrogen atom as the electron pair donor of the metal strings, while the central metal was mostly the element of the transition metals. Therefore, the main point of this research was devoted to the synthesis of lanthanide complexes with oxygen atom as the ligands, rather than traditional synthesis methods. In addition, lanthanide elements are rarely discussed in the general field of chemistry, which makes the study of lanthanide elements very mysterious. Therefore, the basic properties are also the basis of this study, such as atomic radius, ion radius, coordination number and electron configuration.
In the experimental part, there is a main synthesis method, solvent method, using different boiling point solvents regulation of reaction temperature, and to observe the influence of different solubility of reaction, but the exact single crystal structure was not achieved, so mass spectrometry (LR types MALDI) was used as the main analysis method to discover the traces of target by isotopic distribution and mass-spectrum. The monocrystalline structure of [La(OAc)2(DMF)(Chrysazin)]n has been successfully obtained through the integration of solvent and solveothermal methods, and the fundamental properties of [La(OAc)2(Chrysazin)]n have been understood through the instruments. In the future, we also hope to integrate the methods based on this to synthesize more different metal atom strings.

摘要 I
Abstract II
謝誌 IV
目錄 V
表目錄 VIII
圖目錄 IX
式目錄 XVII
第一章 緒論 1
1-1 直線型多核金屬串錯化合物 2
1-1-1 多吡啶胺配基 6
1-1-2 多酚氧配基 8
1-2 金屬-有機配位聚合物 10
1-3 鑭系元素之性質 11
1-3-1 原子半徑與離子半徑 12
1-3-2 電子組態 14
1-3-3 鑭系元素配位數的探討 17
1-4 研究動機 19
第二章 實驗與設計 21
2-1 實驗藥品 22
2-2 實驗儀器 24
2-3 溶劑法－鑭系錯化合物之合成測試 27
2-3-1 溶劑法 27
2-3-2 溶劑法－鑭系錯化合物合成測試 28
2-4 晶體的合成 31
2-4-1 結晶的方法 31
2-4-2 水熱(溶劑熱)反應 33
2-4-3 [La(OAc)2(DMF)(Chrysazin)]n 的合成 35
第三章 結果與討論 36
3-1 溶劑法產物之質譜分析 37
3-1-1 鑭金屬錯化合物質譜分析 37
3-1-2 釹金屬錯化合物質譜分析 42
3-1-3 鐿金屬錯化合物質譜分析 46
3-1-4 鉺金屬錯化合物質譜分析 51
3-1-5 釤金屬錯化合物質譜分析 55
3-2 溶劑法與溶劑熱合成法產物之性質分析-[La(OAc)2(DMF)(Chrysazin)]n 58
3-2-1 晶體結構分析 58
3-2-2 粉末Ｘ-ray繞射圖 62
3-2-3 元素分析 63
3-2-4 熱重分析 64
3-2-5 紅外線光譜 65
第四章 結論 66
第五章 以PBA-b-PCL增韌環氧樹脂之研究 69
5-1 前言 70
5-2 文獻探討與研究方法 71
5-3 PBA-b-PCL的合成 75
5-4性質測試與分析 77
5-5 結論 83
第六章 附錄 84
6-1 X-ray 晶體數據 85
6-2 MASS 圖譜 96
6-3 PBA-b-PCL 之1H NMR 圖譜 122
6-4 參考文獻 124

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