本研究主要利用固態燒結法 (Solid State Sintering) 製備出新穎錫錳鎳 (Sn-Mn-Ni) 氧化物塊材，藉由製成低成本、無毒、對環境友善的錫錳鎳氧化物材料，作為鋰電池 (Lithium Ion Batteries)之陽極材料、光感測器 (Photo-sensors) 及薄膜電晶體 (Thin Film Transistors) 之應用。並經由調整靶材元素比製成塊材及鍍膜的不同後續退火條件，探討薄膜光性及電性，驗證其應用於能源及光電元件之可行性。
本研究主要分為三部分，第一部分是探討新穎 Sn-Mn-Ni 多元氧化物作為鋰電池之陽極材料之可能性。經調整元素比例及優化燒結條件，從掃描式電子顯微鏡 (Scanning Electron Microscopy) 成分分析及X 光能量散佈儀 (X-ray Diffraction) 之結構分析結果得知，SnO2:MnO2:NiO莫耳比例為1:2:1時可形成單相，應用於鋰電池中，可得在100 mA/g定速率下充放電270循環後達到1146 mAh/g的可逆電容量 (Reversible Capacity)，且具98%電容量保持率 (Capacity Retention)，證實錫錳鎳氧化物具有潛力應用於電池之陽極材料。
第二部分以熱蒸鍍成長 Sn-Mn-Ni 多元氧化物薄膜，且藉由調整生胚的成份比例，及薄膜退火環境優化薄膜特性，並搭配 X 光能量散佈儀、紫外/可見光吸收光光譜儀、霍爾效應量測儀等鑑定薄膜特性，如成份比例、結晶性、薄膜吸光率、載子濃度及電阻率等。將此錫錳鎳氧化物材料用來製作光感測器，經由藍光 (460 nm) 照射下，可得上升時間 (Rise Time) 為 41.2 ms 、下降時間 (Fall Time) 為 41.6 ms，光增益 (Gain) 達 31.1，且性質穩定。驗證以 Sn-Mn-Ni 氧化物薄膜作為光電元件的可行性。
第三部分探討以熱蒸鍍成長Sn-Mn-Ni 氧化物薄膜作為半導體層製作薄膜電晶體之可能性，結果顯示薄膜漏電仍需改善，以達到薄膜電晶體的應用。

In this work, a novel, low-cost, non-toxic and environment-friendly tin-manganese-nickel (Sn-Mn-Ni) oxide was synthesized by solid state sintering methods. The applications of tin-manganese-nickel oxide for lithium-ion batteries as anode materials, photo-sensors, and thin-film transistors were investigated. By adjusting composition and sintering conditions, as well as thin film post-annealing conditions. their optical and electrical properties were measured. The feasibility of its application on energy and optoelectronic fields were also demostrated.
This study includes three parts. The first part is to investigate the novel Sn-Mn-Ni oxide as an anode material for lithium-ion batteries. According to the results of Energy Dispersive Spectrum (EDX) analysis in Scanning Electron Microscope and X-ray Diffraction, Sn-Mn-Ni oxide shows a single phase at a molar ratio of the SnO2: MnO2: NiO equal to 1: 2: 1, after composition and process optimization. This Sn-Mn-Ni oxide can be utilized for lithium battery applications as an anode material, showing a high reversible capacity of 1146 mAh/g and a capacity retention of 98% at a current density of 100 mA/g after 270 cycles of operation. It vertified that Sn-Mn-Ni oxide could be used as a potential anode material for lithium-ion batteries (LIBs).
For the second part, the Sn-Mn-Ni oxide for photo-sensors application was investigated by adjusting the composition ratio of green pellet and the post-annealing conditions of thin films. The X-ray energy dispersive spectrometer, EDX, UV-Vis, and Hall-effect measurement were used to characterize thin film properties, such as crystal structure, composition, absorption, carrier concentration, mobility and resistivity. Under the blue light (460 nm) irradiation, the photo-sensor device shows a rise time (tr) of 41.2 ms, fall time (tf) of 41.6 ms and a gain value of 31.1. The result also shows that this Sn-Mn-Ni oxide based photo-sensor is stable and reproducible, indicating the feasibility of its application as a photovoltaic material.
The third part explores the possibility of using Sn-Mn-Ni oxide thin films as a semiconductor layer, deposited by thermal evaporation for thin film tranistors. Results show the leakage of Sn-Mn-Ni oxide thin film needs improvement so as to provide transistor characteristics.

摘要
Abstract
誌謝
目錄
圖目錄
表目錄
第一章 緒論...............................1
第二章 文獻回顧及原理簡介.......3
第三章 實驗流程與儀器介紹......11
第四章 實驗結果與討論............49
第五章 結論...........................100
第六章 未來展望....................103
本研究產出之論文發表...............106
參考文獻....................................106

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