金屬奈米粒子在許多不同領域扮演著重要角色。我們合成了形狀控制的Cu2O和Ag2O奈米粒子。此外，我們已經開發了在還原劑如硼烷銨存在下使用上述半導體奈米晶體合成金屬奈米晶體的合成方法。使用NH3BH3，我們成功地合成了形狀控制的多面體Cu和單個Ag奈米晶體。該方法非常容易合成Cu和Ag菱形十二面體奈米晶體。此外，在安全及一般條件下，我們使用NH3BH3，利用Cu2O奈米晶體催化內部炔烴半氫化和硝基還原的研究。在內部炔烴半氫化反應的情況下，我們獲得了100％轉化率和立體選擇性（Z）-烯烴產物。在還原硝基芳烴的情況下，我們在室溫條件下達到高產率。
在第二章中，我們已經發表了Cu2O立方體，八面體和菱形十二面體可以藉由在50℃或更低的乙醇中在3分鐘內通過氨硼烷還原而被轉化為相同形狀的Cu晶體，證明多面體金屬顆粒來自金屬氧化物晶體的轉換是可行的。氫氣是由氨硼烷所產生的。獲得的Cu晶體內具有略微奈米的孔洞。在加入二苯基乙炔，形成Cu菱形十二面體時的過程中，導致完全立體選擇性地產生（Z）-二苯乙烯。其他炔烴的半氫化也可以得到純的（Z）-烯烴。與CuCl2和商業Cu2O顆粒相比，Cu立方體和八面體表現出優異的（Z）-均二苯乙烯選擇性以及少量的（E）-二苯乙烯和聯芐的形成。機理研究顯示，烯烴在菱形十二面體表面上的低結合親和力導致高產物選擇性。

這些Cu晶體作為合成高純度（Z）-烯烴，是具有高重現性的綠色和低成本催化劑。
我們發表了氧化亞銅立方體，菱形十二面體和八面體奈米晶體對硝基芳烴還原反應的催化研究。在我們的反應研究中，氨硼烷作為還原劑以及氫源。在氨硼烷的存在下，首先在反應時間的5至6分鐘內，這些氧化亞銅奈米晶體完全轉化為銅奈米晶體。這種原位生成的銅奈米晶體成功地催化硝基芳烴還原。我們還研究了使用其他還原劑如NaBH4和N2H4的催化行為。然而，在氨硼烷的情況下，在30℃，25分鐘內可以得到高產率。並且我們還研究了立方體，菱形十二面體和八面體奈米晶體的催化反應行為。
在第四章中，我們研究如何減少試劑對形狀控制的氧化銀到銀奈米晶體形貌轉化的影響。迄今為止，還沒有人從文獻中合成銀菱形十二面體奈米晶體，我們首次報導了使用氫源的銀菱形十二面體奈米晶體合成方法。我們的目標已經達成，我們使用了各種還原劑，但只有氨硼烷的情況下才成功合成氧化銀奈米晶體轉變成形狀維持的銀奈米晶體。氨硼烷充當合成銀奈米晶體的氫源。合成銀奈米晶體的反應方法在非常低的溫度下進行，反應時間也較少。我們成功地從氧化銀立方體，菱形十二面體和八面體合成了銀立方體，菱形十二面體和八面體。還原後，只有氨硼烷的情況下銀奈米晶體的形狀和大小保持不變，但用其他還原劑形成的銀奈米晶體失去了原有的形狀結構和尺寸。

Metal nanoparticles are playing key roles in many different areas. We have synthesized shape-controlled Cu2O and Ag2O nanoparticles. Furthermore, we have developed synthetic methods for using above semiconductor nanocrystals to metal nanocrystals in presence of reducing agent like ammonium borane. Using NH3BH3, we have successfully synthesized shape-controlled polyhedral Cu and single Ag nanocrystals. This method is very easy to synthesis for Cu and Ag rhombic dodecahedra nanocrystals. Additionally, we studied using Cu2O nanocrystals, in the medium of NH3BH3, for the development of safe and general condition for internal alkynes semihydrogenation and nitro reduction catalytic studies. In internal alkynes semihydrogenation reaction case, we have obtained 100% conversion and regioselective (Z)-alkene products. In the case of nitroarenes reduction case also, we achieved high yields at room temperature conditions. Moreover, we have synthesized first time single crystalline Ag rhombic dodecahedra nanocrystals.
In chapter 2, we have reported Cu2O cubes, octahedra, and rhombic dodecahedra can be pseudomorphically converted into Cu crystals of corresponding shapes through reduction by ammonia borane in ethanol at 50 ºC or below within 3 min, demonstrating the feasibility of making challenging polyhedral metal particles from metal oxide crystals. Hydrogen gas is also produced from ammonia borane in the process. The obtained Cu crystals have slightly nanoporous interior. Addition of diphenylacetylene in the formation of Cu rhombic dodecahedra leads to complete stereoselective production of sterically hindered (Z)-stilbene. Semihydrogenation of other alkynes also gives pure (Z)-alkenes. Cu cubes and octahedra also showed excellent (Z)-stilbene selectivity along with minor formation of (E)-stilbene and bibenzyl as compared to CuCl2 and commercial Cu2O particles. Mechanistic studies reveal low binding affinity of alkenes on the rhombic dodecahedra surfaces leads to high product selectivity. These Cu crystals act as green and low-cost catalyst for the synthesis of high-purity (Z)-alkenes with high reproducibility.

In chapter 3, Cu2O cubes, octahedra, and rhombic dodecahedra can be pseudomorphically converted to Cu crystals of the corresponding morphologies through the addition of ammonia borane. Nitroarene can be completely reduced during the compositional transformation with four equivalents of ammonia borane at 30 ºC in 25 min. All the obtained polyhedral Cu crystals can give 100% nitroaniline conversion to p-phenylenediamine exclusively, but commercial Cu2O powder shows a comparatively lower 4-bromonitrobenzene conversion and yields a mixture of products. Use of sodium borohydride as a reducing agent resulted in the formation of deformed Cu particles and a low nitroaniline conversion percentage. Cu2O cubes cannot be converted to Cu particles with the addition of hydrazine, and nitroaniline conversion did not occur. Nitro group reduction is successful with high yields for diverse nitroarene molecules giving only a single product starting from a solution of the nitroarene compound, Cu2O cubes and ammonia borane.

In chapter 4, we have studied here reducing reagent effect on Ag2O to Ag nanocrystal morphology conversion. Till now no one has synthesized Ag rhombic dodecahedra and we are reporting first time Ag rhombic dodecahedra using H-sources. We have used various reducing agents but only ammonia borane case successfully synthesized Ag polyhedra from semiconductor Ag2O nanocrystals. Here, NH3BH3 acts as a hydrogen source for the synthesis of Ag nanocrystals. Synthesis of Ag nanocrystals is done at very low temperatures and short reaction time. We have successfully synthesized Ag cubes, RD and octahedra from Ag2O cubes, RD and octahedra. After reduction Ag nanocrystal shape and size remains same but other reducing agents formed Ag nanocrystals losing their original shapes.

Table of Contents

論文摘要…………………………………………………I
Abstract of the Dissertation………………………III
Table of Contents………………………………………IX
List of Figures…………………………………………XIV
List of Tables…………………………………………XXIV
List of Schemes…………………………………………XXVII
List of Publications…………………………………XXIX

Chapter-I
(1) Ng, C. H. B.; Fan, W. Y. J. Phys. Chem. B 2006, 110, 20801–20807.
(2) Kuo, C.-H.; Huang. M. H. Nano Today 2010, 5, 106–116.
(3) Huang, M. H.; Naresh, G.; Chen, H.-S. ACS Appl. Mater. Interfaces 2018, 10, 4‒15.
(4) Liu, G.; Yu, J. C.; Lu, G. Q.; Cheng, H.-M. Chem. Commun. 2011, 47, 6763−6783.
(5) Chanda, K.; Rej, S.; Liu, S.-Y.; Huang, M. H. ChemCatChem. 2015, 7, 1813‒1817
(6) Kuo, C.-H.; Yang, Y.-C.; Gwo, S.; Huang, M. H. J. Am. Chem. Soc. 2011, 133, 1052−1057.
(7) Tan, C.-S.; Hsu, S.-C.; Ke, W.-H.; Chen, L.-J.; Huang, M. H. Nano Lett. 2015, 15, 2155‒2160.
(8) Ida, Y.; Watase, S.; Shinagawa, T.; Watanabe, M.; Chigane, M.; Inaba, M.; Tasaka, A.; Izaki, M. Chem. Mater. 2008, 20, 1254–1256.
(9) Chen, Y.-J.; Chiang, Y. -W.; Huang, M. H. ACS Appl. Mater. Interfaces 2016, 8, 19672−19679.
(10) Kim, M.; Kim, Y.; Hong, J.-W.; Ahn, S.; Kim, W. Y.; Han, S.W. Chem. Commun. 2014, 50, 9454–9457.
(11) Ho, J.-Y.; Huang, M. H. J. Phys. Chem. C 2009, 113, 14159‒14164.
(12) Huang, W.-C.; Lyu, L.-M.; Yang, Y.-C.; Huang, M. H. J. Am. Chem. Soc. 2012, 134, 1261‒1267.
(13) Chanda, K.; Rej, S.; Huang, M. H. Nanoscale 2013, 5, 12494‒12501.
(14) Rej, S.; Chanda, K.; Chiu, C.-Y.; Chem. ‒Eur. J. 2014, 20, 15991‒15997.
(15) Wang, X.; Wu, H.-F.; Kuang, Q.; Huang, R.-B.; Xie, Z.-X.; Zheng, L.-S. Langmuir 2010, 26, 2774−2778.
(16) Kim, M.-J.; Cho, Y.-S.; Park, S.-H.; Huh, Y.-D. Cryst. Growth Des. 2012, 12, 4180−4185.
(17) Harn, Y.-W.; Yang, T.-H.; Tang, T.-Y.; Chen, M.-C.; Wu, J.-M. ChemCatChem 2015, 7, 80−86.
(18) Rej, S.; Hsia, C.-F.; Chen, T.-Y.; Lin, F.-C.; Huang, J.-S.; Huang, M. H. Angew. Chem., Int. Ed. 2016, 55, 7222‒7226.
(19) Mitsudome, T.; Yamamoto, M.; Maeno, Z.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K. J. Am. Chem. Soc. 2015, 137, 13452−13455.
(20) Yu, C.; Fu, J.; Muzzio, M.; Shen, T.; Su, D.; Zhu, J.; Sun, S. Chem. Mater. 2017, 29, 1413−1418.
(21) Hsia, C.-F.; Madasu, M.; Huang, M. H. Chem. Mater. 2016, 28, 3073‒3079.
(22) Madasu, M.; Hsia, C.-F.; Huang, M. H. Nanoscale 2017, 9, 6970–6974.
(23) Subashchandrabose, T.; Madasu, M.; Hsia, C.-F.; Liu, S.-Y.; Huang, M. H. Chem. Asian J. 2017, 12, 2318‒2322.
(24) Wei, H.; Liu, X.; Wang, A.; Zhang, L.; Qiao, B.; Yang, X.; Huang, Huang, Y.; Miao, S.; Liu, J.; Zhang, T. Nat. Commun. 2014, 5, 5634−5642.
(25) Fountoulaki, S.; Daikopoulou, V.; Gkizis, P. L.; Tamiolakis, I.; Armatas, G. S.; Lykakis, I. N. ACS Catal. 2014, 4, 3504−3511.
(26) Zhang, Z.; Wang, S.-S.; Song, R.; Cao, T.; Luo, L.; Chen, X.; Gao, Y.; Lu, J.; Li, W.-X.; Huang, W. Nat. Commun. 2017, 8, 488–498.
(27) Schimo, G.; Kreuzer, A. M.; Hassel, A. W. Phys. Status Solidi A 2015, 212, 1202–1209.
(28) Sinha, B.; Müllera, R. H.; Möschwitzera, J. P. Int. J. Pharm. 2013, 453, 126–141.

Chapter-II

(1) Shang, Y.; Guo, L. Adv. Sci. 2015, 2, 1500140.
(2) Chanda, K.; Rej, S.; Liu, S.-Y.; Huang, M. H. ChemCatChem. 2015, 7, 1813‒1817.
(3) Kim, M.; Kim, Y.; Hong, J. W.; Ahn, S. .; Kim, W. Y.; Han, S. W. Chem. Commun. 2014, 50, 9454‒9457.
(4) Rej, S.; Chanda, K.; Chiu, C.-Y.; Chem. ‒Eur. J. 2014, 20, 15991‒15997.
(5) Madasu, M.; Hsia, C.-F.; Huang, M. H. Nanoscale 2017, 9, 6970‒6974.
(6) Gawande, M. B.; Goswami, A. .; Felpin, F.-X.; Asefa, T.; Huang, X.; Silva, R. ; Zou, X. ; Zboril, R.; Varma, R. S. Chem. Rev. 2016, 116, 3722‒3811.
(7) Yang, H.-J.; He, S.-Y.; Chen, H.-L.; Tuan, H.-Y. Chem. Mater. 2014, 26, 1785‒1793.
(8) Lu, S.-C.; Hsiao, M.-C.; Yorulmaz, M.; Wang, L.-Y.; Yang, P.-Y.; Link, S.; Chang, W.-S.; Tuan, H.-Y. Chem. Mater. 2015, 27, 8185‒8188.
(9) Hsia, C.-F.; Madasu, M.; Huang, M. H. Chem. Mater. 2016, 28, 3073‒3079.
(10) Subashchandrabose, T.; Madasu, M.; Hsia, C.-F.; Liu, S.-Y.; Huang, M. H. Chem. Asian J. 2017, 12, 2318‒2322.
(11) Zhang, Z.; Wang, S.-S.; Song, R.; Cao, T.; Luo, L.; Chen, X.; Gao, Y.; Lu, J.; Li, W.-X.; Huang, W. Nat. Commun. 2017, 8, 488.
(12) Fedorov, A.; Liu, H.-J.; Lo, H.-K.; Copéret, C. J. Am. Chem. Soc. 2016, 138, 16502‒16507.
(13) Oger, C.; Balas, L.; Durand, T.; Galano, J.-M. Chem. Rev. 2013, 113, 1313‒1350.
(14) Lindlar, H.; Dubuis , R. Org. Synth. 1966, 46, 89.
(15) 15 Teschner, D.; Borsodi, J.; Wootsch, A.; Révay, Z.; Hävecker, M.; Knop-Gericke, A.; Jackson, S. D.; Schlögl, R. Science 2008, 320, 86‒89.
(16) Chan, C. W. A.; Mahadi, A. H.; Li, M. M.-J.; Corbos, E. C.; Tang, C.; Jones, G.; Kuo, W. C. H.; Cookson, J.; Brown, C. M.; Bishop, P. T.; Tsang, S. C. E. Nat. Commun. 2014, 5, 5787.
(17) Slack, E. D.; Gabriel, C. M.; Lipshutz, B. H. Angew. Chem., Int. Ed. 2014, 53, 14051‒14054.
(18) Mitsudome, T.; Takahasi, Y.; Ichikawa, S.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K. Angew. Chem., Int. Ed. 2013, 52, 1481‒1485.
(19) Yun, S.; Lee, S.; Yook, S.; Patel, H. A.; Yavuz, C. T.; Choi, M. ACS Catal. 2016, 6, 2435‒2442.
(20) Long, W.; Brunelli, N. A.; Didas, S. A.; Ping, E. W.; Jones, C. W. ACS Catal. 2013, 3, 1700‒1708.
(21) Laskar, M.; Skrabalak, S. E. ACS Catal. 2014, 4, 1120‒1128.
(22) Studt, F.; Abild-Pedersen, F.; Bligaard, T.; Sørensen, R. Z.; Christensen, C. H.; Nørskov, J. K. Science 2008, 320, 1320‒1322.
(23) Liu, Y.; Liu, X.; Feng, Q.; He, D.; Zhang, L.; Lian, C.; Shen, R.; Zhao, G.; Ji, Y.; Wang, D.; Zhou, G.; Li, Y. Adv. Mater. 2016, 28, 4747‒4654.
(24) Li, G.; Jin, R. J. Am. Chem. Soc. 2014, 136, 11347‒11354.
(25) Mitsudome, T.; Yamamoto, M.; Maeno, Z.; Mizugaki, T.; Jitsukawa, K.; Kaneda, K. J. Am. Chem. Soc. 2015, 137, 13452‒13455.
(26) Yan, M.; Jin, T.; Ishikawa, Y.; Minato, T.; Fujita, T.; Chen, L.-Y.; Bao, M.; Asao, N.; Chen, M.-W.; Yamamoto, Y. J. Am. Chem. Soc. 2012, 134, 17536‒17542.
(27) Kwon, S. G.; Krylova, G.; Sumer, A.; Schwartz, M. M.; Bunel, E. E.; Marshall, C. L.; Chattopadhyay, S.; Lee, B.; Jellinek, J.; Shevchenko, E. V. Nano Lett. 2012, 12, 5382‒5388.
(28) Chernichenko, K.; Madarász, A,; Pápai, I.; Nieger, M.; Leskelä, M.; Repo, T. Nat. Chem. 2013, 5, 718‒723.
(29) Kuo, C.-H.; Chu, Y.-T.; Song, Y.-F.; Huang, M. H. Adv. Funct. Mater. 2011, 21, 792‒797.
(30) Wu, H.-L.; Sato, R.; Yamaguchi, A.; Kimura, M.; Haruta, M.; Kurata, H.;Teranishi, T. Science 2016, 351, 1306‒1310.
(31) Rej, S.; Hsia, C.-F.; Chen, T.-Y.; Lin, F.-C.;Huang, J.-S.; Huang, M. H. Angew. Chem., Int. Ed. 2016, 55, 7222‒7226.
(32) Yurderi, M.; Bulut, A.; Ertas, İ. E.; Zahmakiran, M.; Kaya, M. Appl. Catal. B: Environ. 2015, 165, 169‒175.
(33) Huang, W.-C.; Lyu, L.-M.; Yang, Y.-C.; Huang, M. H. J. Am. Chem. Soc. 2012, 134, 1261‒1267.
(34) Ho, J.-Y.; Huang, M. H. J. Phys. Chem. C 2009, 113, 14159‒14164.
(35) Chan, G. H.; Zhao, J.; Hicks, E. M.; Schatz, G. C.; Van Duyne, R. P. Nano Lett. 2007, 7, 1947‒1952.
(36) Yuan, G.-Z.; Hsia, V; Lin, Z.-W.; Chiang, C.; Chiang, Y.-W.; Huang, M. H. Chem.‒Eur. J. 2016, 22, 12548‒12556.
(37) Li, C. W.; Ciston, J.; Kanan, M. W. Nature 2014, 508, 504‒507.
(38) Nai, J.; Tian, Y.; Guan, X.; Guo, L. J. Am. Chem. Soc. 2013, 135, 16082–16091
(39) Staubitz, A.; Robertson, A. P. M.; Manners, I. Chem. Rev. 2010, 110, 4079‒4124.
(40) Lee, I.; Delbecq, F.; Morales, R.; Albiter, M. A.; Zaera, F. Nat. Mater. 2009, 8, 132‒138.
(41) Fuhrmann, D.; Wacker, D.; Weiß, K.; Hermann, K.; Witko, M.; Wöll, C. J. Chem. Phys. 1998, 108, 2651.
(42) Bridier, B.; Lopez, N.; Ramirez, J. P. Dalton Trans. 2010, 39, 8412-8419.
(43) Koeppel, R. A.; Wehrlia, J. T.; Wainwright, M. S.; Trimm, D. L.; Cant, N. W. Appl. Catal., A 1994, 120, 163-177.

Chapter-III
(1) Yang, H.-J.; He, S.-Y.; Chen, H.-L.; Tuan, H.-Y. Chem. Mater. 2014, 26, 1785‒1793.
(2) Lu, S.-C.; Hsiao, M.-C.; Yorulmaz, M.; Wang, L.-Y.; Yang, P.-Y.; Link, S.; Chang, W.-S.; Tuan, H.-Y. Chem. Mater. 2015, 27, 8185‒8188.
(3) Subashchandrabose, T.; Madasu, M.; Hsia, C.-F.; Liu, S.-Y.; Huang, M. H. Chem. Asian J. 2017, 12, 2318‒2322.
(4) Guo, H.; Chen, Y.; Ping, H.; Jin, J.; Peng, D.-L. Nanoscale 2013, 5, 2394‒2402.
(5) Guo, H.; Chen, Y.; Cortie, M. B.; Liu, X.; Xie, Q.; Wang, X.; Peng, D.-L. J. Phys. Chem. C 2014, 118, 9801‒9808.
(6) Hsia, C.-F.; Madasu, M.; Huang, M. H.. Chem. Mater. 2016, 28, 3073‒3079.
(7) Wang, Y.; Chen, P.; Liu, M.. Nanotechnology 2006, 17, 6000‒6006.
(8) Jin, M.; He, G.; Zhang, H.; Zeng, J.; Xie, Z.; Xia, Y Angew. Chem., Int. Ed. 2011, 50, 10560‒10564.
(9) Chanda, K.; Rej, S.; Huang, M. H. Nanoscale 2013, 5, 12494‒12501.
(10) Chu, C.-Y.; Huang, M. H. J. Mater. Chem. A 2017, 5, 15116‒15123.
(11) Zhang, Z.; Wang, S.-S.; Song, R.; Cao, T.; Luo, L.; Chen, X.; Gao, Y.; Lu, J.; Li, W.-X.; Huang, W.. Nat. Commun. 2017, 8, 488.
(12) Rej, S.; Madasu, M.; Tan, C.-S.; Hsia, C.-F.; Huang, M. H. Chem. Sci. 2018, 9, 2517–2524.
(13) He, D.; Shi, H.; Wu, Y.; Xu, B.-Q. Green Chem. 2007, 9, 849–851.
(14) Xiao, Q.; Sarina, S.; Waclawik, E. R.; Jia, J.; Chang, J.; Riches, J. D.; Wu, H.; Zheng, Z.; Zhu, H. ACS Catal. 2016, 6, 1744–1753.
(15) Andreou, D.; Iordanidou, D.; Tamiolakis, I.; Armatas, G. S.; Lykakis, I. N.. Nanomater. 2016, 6, 54.
(16) Junge, K.; Wendt, B.; Shaikh, N.; Beller, M. Chem. Commun. 2010, 46, 1769–1771.
(17) Wei, H.; Liu, X.; Wang, A.; Zhang, L.; Qiao, B.; Yang, X.; Huang, Huang, Y.; Miao, S.; Liu, J.; Zhang, T. Nat. Commun. 2014, 5, 5634.
(18) Chiu, C.-Y.; Chung, P.-J.; Lao, K.-U.; Liao, C.-W.; Huang, M. H. J. Phys. Chem. C 2012, 116, 23757–23763.
(19) Tsao, Y.-C.; Rej, S.; Chiu, C.-Y.; Huang, M. H. J. Am. Chem. Soc. 2014, 136, 396–404.
(20) Göksu, H.; Can, H.; Şendil, K.; Gültekin, M. S.; Metin, Ö. Appl. Catal. A 2014, 488, 176–182.
(21) Göksu, H.; Ho, S. F.; Metin, Ö.; Korkmaz, K.; Garcia, A. M.; Gültekin, M. S.; Sun, S. ACS Catal. 2014, 4, 1777–1782.
(22) Yu, C.; Fu, J.; Muzzio, M.; Shen, T.; Su, D.; Zhu, J.; Sun, S. CuNi Chem. Mater. 2017, 29, 1413–1418.
(23) Yang, Q.; Chen, Y.-Z.; Wang, Z. U.; Xu, Q.; Jiang, H.-L. Chem. Commun. 2015, 51, 10419–10422.
(24) Vasilikogiannaki, E.; Gryparis, C.; Kotzabasaki, V.; Lykakis, I. N.; Stratakis, M. Adv. Synth. Catal. 2013, 355, 907–911.
(25) Rej, S.; Hsia, C.-F.; Chen, T.-Y.; Lin, F.-C.; Huang, J.-S.; Huang, M. H. Angew. Chem., Int. Ed. 2016, 55, 7222–7226.
(26) Blaser, H.-U. Science 2006, 313, 312–313.
(27) Liu, X.; Li, H.-Q.; Ye, S.; Liu, Y.-M.; He, H.-Y.; Cao, Y. Angew. Chem., Int. Ed. 2014, 53, 7624–7628.
(28) Ke, W.-H.; Hsia, C.-F.; Chen, Y.-J.; Huang, M. H. Small 2016, 12, 3530–3534.
(29) Fountoulaki, S.; Daikopoulou, V.; Gkizis, P. L.; Tamiolakis, I.; Armatas, G. S.; Lykakis, I. N. ACS Catal. 2014, 4, 3504−3511.
(30) Aditya, T.; Jana, J.; Singh, N. K.; Pal, A.; Pal, T. ACS Omega 2017, 2, 1968–1984

Chapter-IV
(1) Kuo, C.-H.; Yang, Y.-C.; Gwo, S.; Huang, M. H. J. Am. Chem. Soc. 2011, 133, 1052−1057.
(2) Chanda, K.; Rej, S.; Liu, S.-Y.; Huang, M. H. ChemCatChem. 2015, 7, 1813‒1817.
(3) Rej, S.; Chanda, K.; Chiu, C.-Y.; Chem.‒Eur. J. 2014, 20, 15991‒15997.
(4) Huang, W.-C.; Lyu, L.-M.; Yang, Y.-C.; Huang, M. H. J. Am. Chem. Soc. 2012, 134, 1261‒1267.
(5) Ho, J.-Y.; Huang, M. H. J. Phys. Chem. C 2009, 113, 14159‒14164.
(6) Tan, C.-S.; Hsu, S.-C.; Ke, W. -H.; Chen, L.-J.; Huang, M. H. Nano Lett. 2015, 15, 2155‒2160.
(7) Lyu, L.-M.; Huang, M. H. J. Phys. Chem. C 2011, 115, 17768‒17773.
(8) Lyu, L.-M.; Wang, W.-C.; Huang, M. H. Chem. Eur. J. 2010, 16, 14167–14174.
(9) Lyu, L.-M.; Huang, M. H. Chem. Asian. J. 2013, 3, 1847–1853.
(10) Chen, Y.-J.; Chiang, Y. -W.; Huang, M. H. ACS Appl. Mater. Interfaces 2016, 8, 19672−19679
(11) Tan, C.-S.; Chen, Y.-J.; Hsia, C.-F.; Huang, M. J. Chem. Asian. J. 2017, 12, 293–297.
(12) Hewavitharana, I. K.; Brock, S. L. ACS Nano. 2017, 11, 11217–11224.
(13) Tsuji, M.; Maeda, Y.; Hikino, S.; Kumagae, H.; Matsunaga, M.; Tang, X.-L.; Matsuo, R.; Ogino, M.; Jiang, P. Cryst. Growth Des. 2009, 9, 4700−4705.
(14) Henzie, J.; Grünwald, M.; Widmer-Cooper, A.; Geissler, P. L.; Yang, P. Nature Mat. 2012, 11, 131–137.
(15) Tao, A.; Sinsermsuksakul, P.; Yang, P. Angew. Chem. Int. Ed. 2006, 45, 4597–4601.
(16) Sun, Y.; Xia, Y. Science 2012, 298, 2176–2179.
(17) Tsao, Y.-C.; Rej, S.; Chiu, C.-Y.; Huang, M. H. J. Am. Chem. Soc. 2014, 136, 396‒404.
(18) Chiang, C.; Huang, M. H. Small 2015, 11, 6018‒6025.
(19) Lin, Z.-W.; Tsao, Y.-C.; Yang, M.-Yi.; Huang, M. H. Chem.–Eur. J. 2016, 22, 2326‒2332.
(20) Schimo, G.; Kreuzer, A. M.; Hassel, A. W. Phys. Status Solidi A 2015, 212, 1202–1209.
(21) Zhang, Z.; Wang, S.-S.; Song, R.; Cao, T.; Luo, L.; Chen, X.; Gao, Y.; Lu, J.; Li, W.-X.; Huang, W. Nat. Common. 2017, 8, 488–498.
(22) Rej, S.; Madasu, M.; Tan, C.-S.; Hsia. C.-F.; Huang, M. H Chem. Sci. 2018, 9, 2517–2524.
(23) Sinha, B.; Müllera, R. H.; Möschwitzera, J. P. Int. J. Pharm. 2013,453, 126–141.